Thursday, September 22, 2011
Q1 Zinc nitrate reacts with aqueous ammonia (NH4OH) to form a salt and a base.
(i) Name the salt and the base.
The salt is zinc hydroxide Zn(OH)2 . The base is Ammonium Nitrate NH4NO3.
(ii) Describe the observations for the reaction.
A white precipitate of zinc hydroxide Zn(OH)2 is formed.
(iii) Write a chemical equation for the reaction.
Zn(NO)3(aq) + 2NH4OH(aq) --> Zn(OH)2(s) + 2NH4NO3(aq)
(iv) Write an ionic equation for the reaction.
Q2 Ammonium sulfate is heated with sodium hydroxide.
(i)Write a chemical equation for the reaction.
(NH4)2SO4 (aq) + 2NaOH (aq) -> Na2SO4 (s) + 2NH3 (g) + 2H2O (l)
(ii) Describe a test for the gas.
Ammonia gas will turn red damp litmus paper to blue in colour.
Q3 An unknown green solution is heated with a piece of aluminium foil and sodium hydroxide solution.
(i) The gas produced turns damp red litmus paper blue. Name the gas evolved.
Ammonia gas
(ii) This is a confirmatory test for an anion. Name this anion.
The anion is Nitrate (NO3-)
(iii) Give a possible cation which gives the green solution.
The possible cation is Iron(III) Fe2+.
Q4 Sulfuric acid is titrated with potassium hydroxide in the preparation of potassium sulfate salt.
(i) Explain why this method is recommended for the preparation for this salt.
Potassium sulfate is a group (I) salt and is soluble.
(ii) Write an ionic equation for the reaction.
Q5 Excess zinc carbonate is added to hydrochloric acid in the preparation of zinc chloride salt.
(i)Write an ionic equation for the reaction
(ii)Why excess zinc carbonate is used?
It is used to ensure that all the hydrochloric acid is completely reacted with the zinc carbonate.
(iii) Briefly explain how the zinc chloride crystals can be obtained.
Step 1: Add excess zinc carbonate solid to beaker of dilute hydrochloric acid until there is excess white zinc carbonate solid left behind.
Step 2: filter to remove the excess unreacted zinc carbonate solid.
Step 3: evaporate the zinc chloride solution to remove water and make a saturated salt solution.
Step 4: the hot saturated solution form zinc chloride salt when it is cooled.